Aqueous-Phase Organometallic Catalysis: Concepts and ApplicationsBoy Cornils, Wolfgang A. Herrmann Now in its second completely revised and expanded edition. Written by the renowned editors B. Cornils and W. A. Herrmann, this book presents every important aspect of aqueous-phase organometallic catalysis, a method which saves time, waste and money. The large-scale application of this "green" technology in chemical industry clearly underlines its practical use outside of academia. New chapters (for example "Organic Chemistry in Water"), 20% more content and fully updated contributions from a plethora of international authors make this book a "must-have" for everyone working in this field. From the reviews of the first edition: "This overview will be extremely useful for everyone active in this field [...]" Angewandte Chemie "This book is an essential in any chemical research library and I strongly recommend it to all synthetic research and teaching chemists. [...]" The Alchemist "The editors are to be congratulated on assembling such a wide range of contributors who have described the industrial as well as the academic aspects of the subject." [...] Journal of Organometallic Chemistry |
Contents
The Way Ahead | 8 |
Basic Aqueous Chemistry | 25 |
W A Herrmann F E Kühn | 44 |
G Laurenczy | 57 |
Catalysts for an Aqueous Catalysis | 69 |
J Kamer J N H Reek P W N M van Leeuwen | 121 |
Tenside Ligands G Papadogianakis | 158 |
W A Herrmann C P Reisinger | 194 |
Kinetics R V Chaudhari B M Bhanage | 364 |
Reaction of Alkenes | 377 |
P W N M van Leeuwen | 391 |
2 | 429 |
3 | 464 |
F E Kühn W A Herrmann | 488 |
W A Herrmann C P Reisinger P Härter | 511 |
14 | 606 |
2 | 219 |
3 | 243 |
4 | 252 |
6 | 272 |
Counterphase Transfer Catalysis T Okano | 288 |
Catalysis Z Jin Y Wang X Zheng | 301 |
M E Davis | 313 |
Aqueous Catalysts for Environment and Safety | 325 |
Typical Reactions | 349 |
15 | 613 |
16 | 627 |
| 635 | |
Catalysis in Fluorous Phases J T Horváth | 646 |
Fluids W Leitner A M Scurto | 665 |
P W N M van Leeuwen | 686 |
in Aqueous Solution S Mecking E Schwab | 699 |
| 727 | |
Other editions - View all
Aqueous-Phase Organometallic Catalysis: Concepts and Applications Boy Cornils,Wolfgang A. Herrmann No preview available - 2006 |
Common terms and phrases
1-octene acid alcohol aldehydes alkenes alkyl allyl amines amphiphilic Angew anion aqueous aqueous phase aqueous solution Aqueous-Phase Organometallic Catalysis B. E. HANSON BAHRMANN BARTIK biphasic systems Boy Cornils C. W. KOHLPAINTNER carbonyl cata Catal cationic Chem chemical Chemistry chiral co-solvents compounds Cornils and Wolfgang diphosphines Edited by Boy enantioselectivity Engl extraction fluorous formation groups H₂ H₂O Hoechst Hoechst AG Homogeneous Catalysis hydroformylation hydrogenation hydrophilic hydrophobic Inorg ionic Joó kinetics Lewis acid ligands liquid phase lyst membrane methanol methyl micellar micelles mixture MONFLIER nonpolar olefins organic phase organic solvents Organomet oxidation palladium phosphines polar polymer polymerization PPh2 presence propene reac reactants reaction rate reactor recycling rhodium Rhône-Poulenc salts Section selectivity separation SINOU sodium solubility solvent substrates sulfonated surfactant Synth synthesis temperature Tetrahedron Lett tion TPPMS TPPTS transition metal two-phase W. A. HERRMANN WIEBUS yields
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