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Synthesis of hydroperoxides
The mixtures of hydroperoxides obtained from nonenzymic oxidations
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2,4-decadienal addition aldehydes allylic amino acids antioxidant activity antioxidative effect arachidonic acid autoxidation autoxidation of methyl carbonyl catalyst chain Chan cholesterol complex concentration containing copper crosslinking decomposition decrease derived dimers double bonds enzymes epoxides Eriksson esters example fatty-acid flavour fluorescent Food Agric formation formed Frankel free radicals Gardner Grosch H-abstraction heavy metals hexanal histidine homolysis hydrogen hydroperoxides hydroperoxy epidioxides inactivation increase induction period inhibited inhibitors initiation isomeric isomers ketone lard linoleic acid linoleic acid hydroperoxide linolenate lipid hydroperoxides lipid oxidation lipid peroxidation lipofuscin lipoxygenase malondialdehyde mechanism membrane metal ions methyl methyl ester methyl linoleate methyl oleate microsomal mixture molecule monohydroperoxides Oil Chem oxidation oxidation products oxy radicals peroxy radicals phospholipid Pokorny polymerization presence pro-oxidative protein reaction rearrangement ROOH Schieberle solvent stability synergists Table Tappel temperature thiol tion tocopherols trans unsaturated fatty acids unsaturated lipids vegetable oils volatile compounds