Electron Paramagnetic Resonance: Elementary Theory and Practical Applications
This book provides an introduction to the underlying theory, fundamentals, and applications of EPR spectroscopy, as well as new developments in the area. Knowledge of the topics presented will allow the reader to interpret of a wide range of EPR spectra, as well as help them to apply EPR techniques to problem solving in a wide range of areas: organic, inorganic, biological, and analytical chemistry; chemical physics, geophysics, and minerology.
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2 MAGNETIC INTERACTION BETWEEN PARTICLES
3 ISOTROPIC HYPERFINE EFFECTS IN EPR SPECTRA
4 ZEEMAN ENERGY g ANISOTROPY
5 HYPERFINE A ANISOTROPY
6 SYSTEMS WITH MORE THAN ONE UNPAIRED ELECTRON
7 PARAMAGNETIC SPECIES IN THE GAS PHASE
8 TRANSITIONGROUP IONS
APPENDIX A MATHEMATICAL OPERATIONS
APPENDIX B QUANTUM MECHANICS OF ANGULAR MOMENTUM
APPENDIX C THE HYDROGEN ATOM AND SELECTED RADICALS RHn
APPENDIX D PHOTONS
APPENDIX E INSTRUMENTATION AND TECHNICAL PERFORMANCE
APPENDIX F EXPERIMENTAL CONSIDERATIONS
APPENDIX G EPRRELATED BOOKS AND SELECTED CHAPTERS
APPENDIX H FUNDAMENTAL CONSTANTS CONVERSION FACTORS AND KEY DATA
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absorption amplitude angular momentum anion anisotropic applied arising axis cavity Chapter Chem components consider constant corresponding crystal detection diagonal dipole effects eigenfunctions eigenvalues Electron Paramagnetic Resonance Electron Spin Resonance ENDOR energy levels EPR line EPR spectrum EPR transitions equations example excitation FIGURE first-derivative free radicals frequency function g ¼ g factor given hamiltonian hence hydrogen atom hyperfine coupling hyperfine interaction hyperfine splittings intensity ions isotropic lineshape linewidth Magn magnetic field Magnetic Resonance magnitude matrix elements measured microwave modulation molecules naphthalene Note nuclear nuclear-spin nuclei observed obtained operator orientation parameters Phys proton proton hyperfine pulse quadrupole Quantum Mechanics quantum number relative relaxation rotation S. S. Eaton sample Section shown in Fig signal solid spectra spectrometer spin hamiltonian spin system spin-lattice relaxation symmetry Table techniques temperature triplet unpaired electron unpaired-electron population vector wavefunction Wiley yields York Zeeman zero
Page 17 - Energy of a classical magnetic dipole in a magnetic field as a function of the angle 6 between the magnetic field and the axis of the dipole: (a) 6=0 (configuration of minimum energy); (b) arbitrary value of 6.