Electronic Spectra of Transition Metal Complexes: An Introductory Text

absorption band angular function angular momentum Assignment atomic orbitals axis bonding C₂ calculation character table charge-transfer cm-¹ cm¯¹ co-ordinates component configuration interaction covalency crystal field theory d-d bands d-d transitions d-electrons d-orbitals d⁹ degen degeneracy direct product distorted electronic configuration electronic spectra electronic transition equation ground group theory identical intensity inter-electron involved Jahn-Teller effect kcm-¹ levels arising ligand field theory ligand orbitals linear combinations metal ion metal orbitals metal-ligand Mn2+ molecular orbitals molecule nephelauxetic Ni² octahedral complexes octahedral field orbital angular Orgel diagram parameters plane point group quantum number result rotation shown in Fig spectrum spin triplet spin-allowed transitions spin-orbital coupling splitting square complexes subshell symmetry elements symmetry operation symmetry species t₂ t₂g Tanabe-Sugano diagram tetrahedral complexes tion transition metal complexes triply degenerate vector vibrational vibronic transitions wave function wavenumber weak field whilst