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Symmetry and the Point Groups
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absorption Amer anisotropic application assigned atomic orbitals atoms axes axis band basis set bond calculated carbon Chem chemical shift complex components compounds contribution coordinate corresponding coupling constant crystal curve determine diamagnetic dipolar dipole discussed effect electron density electronic transitions equation example excited field gradient FIGURE frequency give rise given ground Hamiltonian hydrogen hyperfine hyperfine coupling illustrated in Fig indicated infrared Inorg intensity interaction ionization iron(III irreducible representations isomer isotropic lattice ligand magnetic field metal ion molecular orbital molecule nmr spectrum nuclear nucleus observed obtained occur octahedral orientation paramagnetic parameters peaks perpendicular Phys plane point group polarized proton pulse quadrupole R. S. Drago radiation Raman referred relaxation resonance result rotation sample shown in Fig solution solvent spectra spectroscopy spin density spin-orbit coupling splitting structure symmetry operations Table temperature term transition metal unpaired electron vector vibrational wave functions z-axis zero