Standard Potentials in Aqueous SolutionThe best available collection of thermodynamic data!The first-of-its-kind in over thirty years, this up-to-date book presents the current knowledgeon Standard Potentials in Aqueous Solution.Written by leading international experts and initiated by the IUPAC Commissions onElectrochemistry and Electroanalytical Chemistry, this remarkable work begins with athorough review of basic concepts and methods for determining standard electrodepotentials. Building upon this solid foundation, this convenient source proceeds to discussthe various redox couples for every known element.The chapters of this practical, time-saving guide are organized in order of the groups ofelements on the periodic table, for easy reference to vital material . AND each chapteralso contains the fundamental chemistry of elements ... numerous equations of chemicalreactions .. . easy-to-read tables of thermodynamic data . . . and useful oxidation-statediagrams.Standard Potentials in Aqueous Solution is an ideal, handy reference for analytical andphysical chemists, electrochemists, electroanalytical chemists, chemical engineers, biochemists, inorganic and organic chemists, and spectroscopists needing information onreactions and thermodynamic data in inorganic chemistry . And it is a valuable supplementarytext for undergraduate- and graduate-level chemistry students |
Contents
Its Significance | 13 |
Hydrogen Philip N Ross | 39 |
Oxygen James P Hoare | 49 |
39 | 66 |
Bromine Torquato Mussini and Paolo Longhi | 78 |
Lepri and Daniela Heimler | 84 |
Nitrogen Phosphorus Arsenic Antimony and Bismuth | 127 |
Carbon Silicon Germanium Tin and Lead Zbigniew Galus | 189 |
Manganese Technetium and Rhenium | 429 |
Chromium Molybdenum and Tungsten | 453 |
Vanadium Niobium and Tantalum | 507 |
Titanium Zirconium and Hafnium | 539 |
Boron Aluminum and Scandium | 555 |
Yttrium Lanthanum and the Lanthanide Elements | 587 |
The Actinides L Martinot and J Fuger | 631 |
Beryllium Magnesium Calcium Strontium Barium | 675 |
Gallium Indium and Thallium V V Losev | 237 |
Zinc Cadmium and Mercury | 249 |
Copper Silver and Gold | 287 |
Nickel Palladium and Platinum | 321 |
Cobalt Rhodium and Iridium | 367 |
Iron Ruthenium and Osmium | 391 |
Lithium Sodium Potassium Rubidium Cesium and Francium | 727 |
Inert Gases Bruno Jaselskis | 763 |
Synopsis of Standard Potentials | 787 |
803 | |
829 | |
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Common terms and phrases
A H°/kJ mol A. J. Bard Acid Solution Actinide AH/kJ mol alkaline solutions anion anodic aqueous solutions Basic Solution Bureau of Standards calculated cell Chem Chemical Thermodynamic Chemistry complexes compounds concentration couple Description State AH/kJ difluoride Electrochem Electrochemistry electrode reaction Elements energy of formation entropy equilibrium constant estimated experimental fluoride formal potential Formula Description Gibbs energy given in Table Go/kJ mol H₂O half-reaction hydrogen hydrolysis hydroxide Inorg Khim kJ mol kJ mol-1 lanthanides ligands measurements metal mol S°/J mol So/J mol niobium Nucl obtained oxidation oxygen perxenate Phys Potential Diagrams Pourbaix redox reduction reported species stable standard electrode potential standard potential sulfur TABLE 1 Continued temperature coefficient tetraoxotungstate thermodynamic data Thermodynamic Properties tion Tungsten U.S. Government Printing Undiss values vanadium(III W. H. Evans xenon xenon difluoride xenon hexafluoride مة