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Optical Isomerism Due to Asymmetric Carbon Atoms
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acetic acid Fig addition alcohol angle anti asymmetric atoms asymmetric carbon atoms asymmetric synthesis axial biphenyl bromine carbanion carbonium ion carbonyl Chap Chem chemical chim chloride cis and trans cis isomer CO2H compounds configuration conformation correlation corresponding Cotton effect crystal curve cyclic cyclohexane derivatives dextrorotatory diastereoisomers difference dipole dissymmetric Djerassi dl pair double bond electrons enantiomers energy epimerization epoxide equatorial equilibrium ester example formation gauche geometrical isomers gives hydrogen hydroxyl hydroxyl group ibid infrared interaction intermediate involves isomerism kcal./mole ketone meso form method methyl methyl groups methylene mixture molecular molecule obtained olefins optically active Organic Chemistry oxidation phenyl planar plane polarized polymer racemic reaction reagent rearrangement reduction resolution ring rotation rotatory dispersion shown in Fig solvent solvolysis stable starting material stereochemical stereochemistry stereoisomers stereoselective steric strain substituents symmetry synthesis tartaric acid tion tosylate trans isomer transition whereas