Optical Properties of Metal ClustersOptical Properties of Metal Clusters deals with the electronic structure of metal clusters determined optically. Clusters - as state intermediate between molecules and the extended solid - are important in many areas, e.g. in air pollution, interstellar matter, clay minerals, photography, heterogeneous catalysis, quantum dots, and virus crystals. This book extends the approaches of optical molecular and solid-state methods to clusters, revealing how their optical properties evolve as a function of size. Cluster matter, i.e. extended systems of many clusters - the most frequently occuring form - is also treated. The combination of reviews of experimental techniques, lists of results and detailed descriptions of selected experiments will appeal to experts, newcomers and graduate students in this expanding field. |
Contents
| 1 | |
| 6 | |
| 13 | |
2 | 14 |
d Penetration Depth of Electromagnetic Waves in Metals | 21 |
4 | 24 |
6 | 42 |
e Nonlinear Optical Effects | 69 |
3 | 211 |
4 | 223 |
6 | 261 |
7 | 268 |
Experimental Results and Discussion | 275 |
2 | 333 |
3 | 366 |
c Other Shell Clusters | 375 |
g Longitudinal Plasmons | 75 |
7 | 102 |
9 | 129 |
10 | 135 |
88 | 142 |
11 | 148 |
Experimental Methods | 203 |
4 | 395 |
Appendix | 437 |
Survey of Optical Spectra of Elemental Metal Clusters | 451 |
Mie Computer Program | 473 |
| 483 | |
| 527 | |
Other editions - View all
Common terms and phrases
Ag clusters atoms band bulk calculations Chem chemical clus cluster beam cluster matter cluster samples cluster shapes cluster sizes cluster surface coalescence colloidal conduction electrons contributions density dependence dielectric function dipole distribution effective medium electric electromagnetic ellipsoids embedded energy example experimental experiments extinction constant extinction spectra Ɛeff field filling factors free clusters frequency geometry glass Hence hydrosol interactions interband transitions interface investigated ionization ions jellium Kreibig large clusters laser Lett light Lorentz-Lorenz material matrix Maxwell Garnett metal clusters methods Mie theory modes multipoles noble metals nonlinear optical optical properties optical response optical spectra oscillator strength parameter particles photon Phys Physik polaritons polarizability polarization processes quasi-static Raman scattering red shift resonance samples scattering Sect shell shift single clusters small clusters solid spectroscopy spectrum sphere spherical spheroids structure substrate surface plasmon temperature theoretical theory tion topology wavelength Wavelength nm width