Advances in CatalysisSince 1948, Advances in Catalysis has filled the gap between the papers that report on and the textbooks that teach in the diverse areas of catalysis research. The editors of and contributors to Advances in Catalysis are dedicated to recording progress in this area. Advances in Catalysis, Volume 46 builds foundations of fundamental understanding at the atomic and molecular scales in support of technologically important catalytic processes. The first tow chapters forge links between molecular (homogeneous) catalysis and catalysis occurring analogously-and sometimes more successfully-on surfaces. The following three chapters are concerned with advances in classical surface catlysis building on concepts of reaction kinetics and surface characterization. |
Contents
| 1 | |
Chapter 2 Olefin Polymerization Catalyzed by Metallocenes | 89 |
Analysis of Reaction Schemes | 161 |
Chapter 4 Surface Structures of Oxides and Halides and Their Relationships to Catalytic Properties | 265 |
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Common terms and phrases
adsorbed adsorbed species adsorption alkyl anions aromatic atoms band C–N bond calculations carbon Catal catalytic activity cations centers Chem chemical chemistry chiral cobalt compounds coordination coverage Cr3+ cyclohexene dehydrogenation edge electron energy entropy epoxidation equilibrium constant ethyl ethylene faces Faraday Trans formation formed frequency groups hydrocarbons hydrogen hydrogenolysis hydrotreating hydroxyl immobilized interaction investigated ions isobutane isobutylene isotactic Kaminsky kinetic model kinetic parameters kJ/mol Lett Lewis acid ligands Macromol metallocene catalysts Mg2+ microcrystals molecular molecules molybdenum monomer Morterra MoS2 nickel nitrogen observed olefins oxidation oxygen Phys piperidine polymer polymerization polypropylene porphyrin pressure probe properties propylene pyridine quinoline rate constant reactants reaction kinetics reaction scheme reactive reactor samples silica sintered solid solutions spectra spectroscopy stable step structure sulfided sulfur Surf surface species t-BuOOH temperature tion transition metal values Zecchina zeolite