Modern Electrochemistry: An Introduction to an Interdisciplinary Area7 The Electrified Interface.- 7.1 Electrification of an Interface.- 7.1.1 The Electrode-Electrolyte Interface: The Basis of Electrodics.- 7.1.2 New Forces at the Boundary of an Electrolyte.- 7.1.3 The Interphase Region Has New Properties and New Structures.- 7.1.4 An Electrode Is Like a Giant Central Ion.- 7.1.5 The Consequences of Compromise Arrangements: The Electrolyte Side of the Boundary Acquires a Charge.- 7.1.6 Both Sides of the Interface Become Electrified: The So-Called "Electrical Double Layer"--7.1.7 Double Layers Are Characteristic of All Phase Boundaries.- 7.1.8 A Look into an El. |
Contents
| 623 | |
| 624 | |
| 630 | |
| 639 | |
8 | 667 |
CHAPTER 1 | 714 |
Further Reading | 717 |
9 | 719 |
Further Reading | 1017 |
CHAPTER 11 | 1024 |
Further Reading | 1035 |
6 Relation Between Calculated and Observed Activity | 1046 |
Further Reading | 1079 |
3 | 1092 |
Further Reading | 1093 |
Further Reading | 1110 |
1 | 736 |
CHAPTER 8 | 748 |
2 | 768 |
Further Reading | 790 |
CHAPTER 2 | 792 |
Further Reading | 801 |
Electrodics | 803 |
Protons in Solution | 813 |
lonSolvent Interactions | 817 |
Further Reading 250 | 823 |
CHAPTER 6 | 824 |
Further Reading | 835 |
Further Reading | 841 |
9 | 896 |
Further Reading | 909 |
Further Reading | 929 |
Further Reading | 946 |
269 | 968 |
Further Reading | 986 |
CHAPTER 3 | 998 |
2 | 1002 |
lonlon Interactions | 1016 |
Further Reading | 1137 |
CHAPTER 4 | 1146 |
Function? | 1149 |
lon Transport in Solutions | 1158 |
Further Reading | 1172 |
3 | 1177 |
Further Reading | 1196 |
Further Reading | 1230 |
96 | 1233 |
108 | 1239 |
2 | 1253 |
Some Electrochemical Systems of Technological Interest | 1265 |
Further Reading | 1349 |
4 | 1395 |
Further Reading | 1400 |
5 | 1409 |
Further Reading | 1432 |
| xxxii | |
| xxxiii | |
| xxxviii | |
| xli | |
Common terms and phrases
adion concentration adsorbed adsorption anodic assumed atoms bulk Butler-Volmer equation capacity cathodic cell potential charge density charge transfer charge-transfer charge-transfer reaction chemical considered contact adsorption contact-adsorbed ions corrosion coverage crystal current density curve de-electronation depends deposition determination dipole dissolution distance double layer elec electric field electrified interface electrocatalyst electrochemical Electrochemistry electrode charge electrode potential electrode surface electrodeposition electrodic reaction electrolyte electron acceptors electron-source equal equilibrium potential ethylene exchange-current density experimental free energy function H₂ H₂O Hence hydrated hydrogen evolution increases interaction interphase ionic ions lattice linear measured mechanism metal-solution interface mole negative Nernst equation obtained overall reaction overpotential oxidation oxygen particles phase plane platinum positive potential difference proton reactants reaction rate region screw dislocation Section semiconductor solution species step substrate surface excess tion tunneling valence band variation versus water molecules zero ΔΦ