Comprehensive Organic Functional Group Transformations: Synthesis: carbon with one heteroatom attached by a multiple bond |
Contents
Tricoordinated Carbon Functions R₂CY | 3 |
Tricoordinated Carbon Functions Bearing Two Heteroatoms R₂CCXX | 4 |
Dicoordinate Carbon Functions with Two Doubly Bonded Heteroatoms YCY | 5 |
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a,ẞ-unsaturated aldehydes a,ẞ-unsaturated ketones acetals acid chlorides acyl addition alcohols aldehydes alkenes alkyl alkynes allylic amines amino Angew anhydride anion aromatic aryl benzaldehydes benzyl bond Bu"Li Bull carbene carbene complexes carbon carbonyl carbonyl compounds catalyst Chem chemistry Chim CO₂Et CO₂Me Commun corresponding cyanide cyclic cycloaddition deprotonation derivatives diazo electrophilic elimination enamines Engl epoxides esters Et2O Et3N example formation formyl give Grignard reagents H₂O halides heteroatom Heterocycl high yield hydrazones hydride hydrogen hydrolysis imines intermediate isocyanides isolated Justus Liebigs Ann ketene ketenimines ketones lithium MeO2C metal method methyl nitriles nitro NMe2 nucleophilic Organomet oxidation oximes Perkin Trans phosphine PPh3 prepared presence pyridine react reaction reactive rearrangement reduction reported RI R2 salts Scheme silyl enol ethers sodium substituted substrates sulfide sulfur Synth synthesis Tetrahedron Lett thioaldehydes thioketones treatment undergo unsaturated vinyl ylides