Basic Principles of Spectroscopy |
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Page 12
... given in the standard texts on quantum mechanics . Here we shall simply quote the results . The energy E , which appears only in Eq . ( 1-39 ) , is given by En = - μe1 2n2h2 ( 1-41 ) where n , the principal quantum number , has the ...
... given in the standard texts on quantum mechanics . Here we shall simply quote the results . The energy E , which appears only in Eq . ( 1-39 ) , is given by En = - μe1 2n2h2 ( 1-41 ) where n , the principal quantum number , has the ...
Page 16
... given by 24 + 21E ¥ h2 = 0 ( 1-49 ) where the laplacian operator is given in terms of polar coordinates as 1 V2 = 2 r2 sin 0 ( a [ sin ( a / a0 ) ] 1 22 20 The solution of Eq . ( 1-49 ) gives + sin 0 2 h2 E = J ( J + 1 ) 21 ( 1-50 ) ...
... given by 24 + 21E ¥ h2 = 0 ( 1-49 ) where the laplacian operator is given in terms of polar coordinates as 1 V2 = 2 r2 sin 0 ( a [ sin ( a / a0 ) ] 1 22 20 The solution of Eq . ( 1-49 ) gives + sin 0 2 h2 E = J ( J + 1 ) 21 ( 1-50 ) ...
Page 131
... given by h B = cm - 1 4πсI ( 7-2 ) THE SELECTION RULE The quantum mechanical selection rule for a transition between any two rotational levels is given by μnm = μ [ V μm dr ( 7-3 ) where is the permanent dipole moment of the molecule ...
... given by h B = cm - 1 4πсI ( 7-2 ) THE SELECTION RULE The quantum mechanical selection rule for a transition between any two rotational levels is given by μnm = μ [ V μm dr ( 7-3 ) where is the permanent dipole moment of the molecule ...
Contents
PREFACE | 1 |
NUCLEAR QUADRUPOLE RESONANCE SPECTROSCOPY | 29 |
NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY | 52 |
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