Basic Principles of Spectroscopy |
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Page 62
... split the methyl absorption peak into three lines of relative intensities 1 : 2 : 1 . Likewise , the methylene peak is ... splitting due to this spin - spin interaction , unlike the chemical shift , is independent of the applied field ...
... split the methyl absorption peak into three lines of relative intensities 1 : 2 : 1 . Likewise , the methylene peak is ... splitting due to this spin - spin interaction , unlike the chemical shift , is independent of the applied field ...
Page 118
... splitting . The size of the zero - field splitting varies according to the type of molecules , but are usually of the same order as the splitting due to a strong magnetic field ( about 3000 G ) . Figure 6-10 shows a typical splitting ...
... splitting . The size of the zero - field splitting varies according to the type of molecules , but are usually of the same order as the splitting due to a strong magnetic field ( about 3000 G ) . Figure 6-10 shows a typical splitting ...
Page 139
... splitting of the rotational levels as a result of the coupling . The selection rules for the transition are AJ = +1 AF = 0 , 1 = Thus it is possible to obtain the nuclear quadrupole coupling constant eQq from the fine structure of the ...
... splitting of the rotational levels as a result of the coupling . The selection rules for the transition are AJ = +1 AF = 0 , 1 = Thus it is possible to obtain the nuclear quadrupole coupling constant eQq from the fine structure of the ...
Contents
PREFACE | 1 |
NUCLEAR QUADRUPOLE RESONANCE SPECTROSCOPY | 29 |
NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY | 52 |
Copyright | |
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absorption angular momentum applied atomic orbitals axis bands benzene bond Chap Chem chemical shift Chemistry components compounds constant coordinates diagram diatomic molecule dipole discussed Educ effect electric field electronic transition emission energy levels equation example excited fluorescence frequency given hence intensity interaction ionization potential irreducible representation laser linear lines magnetic field magnetic moment Magnetic Resonance matrices McGraw-Hill Book Company Microwave Spectroscopy molecular orbital Mössbauer Mössbauer Effect normal modes Nuclear Magnetic nuclear quadrupole nucleus obtained optically active oscillator permission phosphorescence photoelectron Phys plane point group polarized potential energy protons quantum mechanics quantum number R₂ radiation Raman selection rules shown in Fig shows solution spectra spectrometer spectrum spin-spin splitting structure studies symmetry elements symmetry operations Table technique tion triplet unpaired values vector wave function wavelength Wiley & Sons York Zeeman zero ΔΕ