Stereochemistry Conformation and MechanismThe Revised Sixth Edition Has Been Designed As An Entirely New And Modern Mature Text Book To Provide A Conceptual Tool In The Hands Of A Student To Learn Aspects Of Modern Stereochemistry Conformation And Mechanism.New Edition Is Intended To Provide Specialized Knowledge For The Student To Excel At Any Level-University Examination, Competitive Examinations E.G., Net And Before Interview Boards Etc. It Also Largely Covers New Ugc Curriculum And Includes Following Topics : * Chirality (Including Stereospecificity And Stereoselectivity). * Prostereoisomerism/Prochirality (Including Asymmetric Synthesis). * Aliphatic Nucleophilic Substitution (Including Nonclassical Carbocations). * Conformations And Stereoisomerism Of Acyclic And Cyclic Systems (Including Conformation Of Sugars). * Stereochemistry Of Elimination Reactions. * Stereochemistry Of Some Additions To Carbon-Carbon Multiple Bonds. * Addition To Carbon Hetero Multiple Bonds-Stereochemistry And Mechanism. * Pericyclic Reactions (Including Fmo, Pmo Approach And Co-Relation Diagrams). * Aliphatic Electrophilic Substitution. * In This Revised Sixth Edition, New Examples, Discussion And Diagrams Have Been Added In Every Topic To Make The Subject More Understandable. |
Contents
Section 1 | 10 |
Section 2 | 22 |
Section 3 | 37 |
Section 4 | 40 |
Section 5 | 50 |
Section 6 | 74 |
Section 7 | 109 |
Section 8 | 111 |
Section 9 | 116 |
Section 10 | 120 |
Section 11 | 129 |
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Common terms and phrases
2-butanol absolute configuration achiral alkene allene alternating axis amine amino acids assign asymmetric transformation atropisomers axial chirality axis of symmetry biphenyl bromine carbon atom center of symmetry chiral compound chiral molecule chiral plane cis and trans crystallization cyclic cyclohexane descriptors diastereomers dissymmetric double bond drawn eclipsed conformation enantiomeric forms enantiomers enzyme erythro example exist Fischer projection four stereoisomers gives glucose glyceraldehyde group of lowest helical hydrogen identical interchange interconvert isomerism ligands lowest priority maleic acid meso compound meso-tartaric acid mirror image molecule nitrogen nomenclature OH group optically active orientation pair of enantiomers perpendicular pilot atom planar planar chirality plane of paper plane of symmetry point group racemic mixture reaction reagent resolution resolved ring rotation sawhorse Scheme 1.2a shown staggered conformation stereo stereocenter stereochemical stereogenic carbon stereoisomers stereoselective structure substituted superimposable symmetry elements tartaric acid term chiral tetrahedral three dimensional threo tion trans isomers trans-cyclooctene