Pincer Compounds: Chemistry and ApplicationsDavid Morales-Morales Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research—from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this fascinating and promising area. Over a decade since the publication of Morales-Morales and Jensen’s The Chemistry of Pincer Compounds (Elsevier 2007), research in this unique area has flourished, finding a plethora of applications in almost every single branch of chemistry—from their traditional application as very robust and active catalysts all the way to potential biological and pharmaceutical applications.
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Contents
1 | |
19 | |
47 | |
67 | |
5 Mechanistic Insights and Computational Prediction of Base Metal Pincer Complexes for Catalytic Hydrogenation and Dehydrog | 101 |
6 Hydrogenation and Dehydrogenation Reactions Catalyzed by Iron Pincer Compounds | 111 |
A New Frontier | 133 |
Structural Diversity and Applications | 173 |
Trans Influence and Functionality | 401 |
20 Transition Metal Complexes With Anionic SulfurBased Pincer Ligands | 415 |
21 Metalation and Transmetalation Chemistry of Pyridine and ArylLinked BisNHC Pincer Ligands | 431 |
22 Unsymmetrical Pincer Palladacycles Synthesis and Reactivity | 451 |
23 BenzeneDerived Organometallic Pincer Compounds Bearing SixMembered Metallacycles and Up | 467 |
24 Chemistry of Mn and Co Pincer Compounds | 491 |
25 Selective Deuteration of Organic Compounds Catalyzed by Ruthenium Pincer Complexes | 519 |
New Pathways to Innovative Pincer Architectures | 539 |
Synthesis and Asymmetric Catalysis | 191 |
10 Chiral NCN PincerType Catalysts Having Bisimidazolines | 219 |
11 Transition Metal Pincer Complexes with a Central sp3Hybridized Carbon Atom | 237 |
Synthesis Applications and Catalysis | 251 |
Approaches With Water as Solvent Reagent and Molecular Hydrogen Storage | 273 |
14 Pincers Based on Dicarboxamide and Dithiocarboxamide Functional Groups | 295 |
15 Pincer Complexes of Iron and Their Application in Catalysis | 327 |
16 Osmium Complexes With POP Pincer Ligands | 341 |
Synthesis Electronic Structure and Reactivity | 359 |
18 Pincer Iridium and Ruthenium Complexes for Alkane Dehydrogenation | 383 |
27 Use of Pincer Compounds as MetalBased Receptors for Chemosensing of Relevant Analytes | 587 |
28 Advances in the Design and Application of RedoxActive and Reactive Pincer Ligands for Substrate Activation and Homogene | 599 |
29 The Chemistry of Bisphosphomide and 12Phenylenediamine Based PBP Pincer Transition Metal Complexes and Catalytic Appli | 623 |
30 LigandIntroduction Synthesis of NCNPincer Complexes and their Chemical Properties | 643 |
An Overview of Synthesis Reactivity Photoluminescence and Biological Applications | 673 |
Classical Versus Nonclassical Coordination Modes at Ru Rh Ir and Pt | 701 |
33 Conclusions and Personal Comment | 711 |
715 | |
Back Cover | 737 |