Nature, Volume 452Sir Norman Lockyer Macmillan Journals Limited, 2008 - Electronic journals |
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Page 164
... ketyl radical ( red ) . The ketyl radical then loses hydrogen and oxygen atoms as a water molecule , forming an allylic ketyl radical ( green ) . This is the first example of a radical enzyme mechanism in which the substrate is reduced ...
... ketyl radical ( red ) . The ketyl radical then loses hydrogen and oxygen atoms as a water molecule , forming an allylic ketyl radical ( green ) . This is the first example of a radical enzyme mechanism in which the substrate is reduced ...
Page 239
... ketyl radical bound to the enzyme by electron paramagnetic resonance spectroscopy employing isotope - labelled ( R ) -2 - hydroxy - 4 - methylpentanoyl - CoA species . We also found that the enzyme generated the stabilized pentadienoyl ...
... ketyl radical bound to the enzyme by electron paramagnetic resonance spectroscopy employing isotope - labelled ( R ) -2 - hydroxy - 4 - methylpentanoyl - CoA species . We also found that the enzyme generated the stabilized pentadienoyl ...
Page 241
... ketyl radical . Support is also found n the magnitude of the 13C hyperfine coupling constant and absence Of coupling with the CH2 moiety of CoA ( see Supplementary Discussion and Supplementary Tables 3 and 4 ) . The conformation of the ...
... ketyl radical . Support is also found n the magnitude of the 13C hyperfine coupling constant and absence Of coupling with the CH2 moiety of CoA ( see Supplementary Discussion and Supplementary Tables 3 and 4 ) . The conformation of the ...
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