Physical Organic ChemistryPhysical Organic Chemistry deals with reaction mechanisms and with the experimental techniques and logical connections used in the establishment of a consistent theory of organic chemistry. |
Contents
Models of chemical bonding | 1 |
Kinetics and thermodynamics | 77 |
Reagents and reaction mechanisms | 114 |
Copyright | |
17 other sections not shown
Common terms and phrases
acetate acid AcOH activation addition alkene alkyl Amer anion aromatic atom base benzene carbanion carbon carbonyl catalysis cation CH₂ charge Chem chemical CN CN coefficients compounds conformation conjugated constant correlation cycloadditions dipole dissociation electron electron-withdrawing electrophilic elimination enthalpy entropy enzyme equation equilibrium ester EtOH example formation frontier orbitals geometry H H H H₂O halides Hammett Hammett equation HOMO hydrolysis increase interaction intermediate ion-pair ionization isomers isotope effects kcal kcal mol-¹ kinetic kinetic isotope effect kJ mol¹ Krel leaving group linear LUMO mechanism methyl mol¯¹ molecules NO₂ nucleophilic observed occur Organic Chemistry ortho oxygen parameter pathway Ph Ph Phys plot polar proton proton transfer radical rate-determining reaction center reaction coordinate reactivity reagents rearrangement resonance ring solution solvation solvent solvolysis species stability steric steric effects structure substituent substrate Table tert-Bu Tetrahedron Letts transition values