Pincer compounds : chemistry and applications
David Morales-Morales (Editor)
Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research-from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this fascinating and promising area. Over a decade since the publication of Morales-Morales and Jensen's The Chemistry of Pincer Compounds (Elsevier 2007), research in this unique area has flourished, finding a plethora of applications in almost every single branch of chemistry-from their traditional application as very robust and active catalysts all the way to potential biological and pharmaceutical applications. Source other than the Library of Congress
xvii, 736 pages : illustrations ; 28 cm
9780128129319, 012812931X
1000030377
1. Chiral pincer complexes for asymmetric reactions
2. Well-defined iron and manganese pincer catalysts
3. The pincer complexes of Group 13-15 elements: recent developments
4. Reduction of CO2 mediated or catalyzed by pincer complexes
5. Mechanistic insights and computational prediction pincer complexes for catalytic hydrogenation and dehydrogenation reactions
6. Hydrogenation and dehydrogenation reactions catalyzed by iron pincer compounds
7. Actinide pincer chemistry: a new frontier
8. Complexes of NHC-based CEC pincer ligands: structural diversity and applications
9. Transition metal pincer complexes with chiral imidazoline donor(s): synthesis and asymmetric catalysis
10. Chral NCN pincer-type catalysts having bis(imidazoline)s
11. Transition metal pincer complexes with a central sp3-hybridized carbon atom
12. CCC-NHC pincer compleses: synthesis, applications, and catalysis
13. Metal pincer complexes in aqueous media: approaches with water as solvent, reagent, and molecular hydrogen storage
14. Pincers based on dicarboxamide and dithiocarboxamide functional groups
15. pincer complexes of iron and their application in catalysis
16. Osmium complexes with POP pincer ligands
17. Pincer carbenoid complexes withj late transition metals: synthesis, electronic structure, and reactivity
18. Pincer iridium and ruthenium complexes for alkane dehydrogenation
19. Silicon-based pincers: trans influence and functionality
20. Transition metal complexes with anionic sulfur-based pincer ligands
21. Metalation and transmetalation chemistry of pyridine- and aryl-linked Bis-NHC pincer ligands
22. Unsymmetrical pincer palladacycles synthesis and reactivity
Benzene-derived organometallic pincer complexes bearing six-membered metallacycles and up
Chemistry of Mn and Co pincer compounds
25. Selective deuteration of organic compounds catalyzed by ruthenium pincer complexes
26. [sigma]-organometallic chemistry with 2.6-bis(imino)pyridine ligands: new pathways to innovative pincer architectures
27. Use of pincer compounds as metal-based receptors for chemosensing of relevant analytes
28. Advances in the design and application of redox-active and reactive pincer ligands for substrate activation and homogeneous catalysis
29. The chemistry of bisphosphomide and 1,2-phenylenediamine based PBP pincer transition metal complexes and catalytic applications
30. Ligand-introduction synthesis of NCN-pincer complexes and their chemical properties
31. Pincer complexes of gold: an overview of synthesis, reactivity, photoluminescence, and biological applications
32. Semirigid pincer-like SiPSi ligands: classical versus nonclassical coordination modes at Ru, Rh, Ir, and Pt
33. Conclusions and personal comment